The expressions (c 11 ) 2 + c 11 c 21 S 12 and (c 12 )

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The expressions (c11)2 + c11c21S12 and (c12)2 + c11c21S12 for the probability of finding an electron on the H and F atoms in HF, respectively, were derived in Section 23.8. Use your results from Problem P23.21 and these expressions to calculate the probability of finding an electron in the bonding orbital on the F atom for SHF = 0.075, 0.18, and 0.40. Explain the trend shown by these results.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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