Ultraviolet radiation photolyses O 3 to O 2 and O. Determine the rate at which ozone is

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Ultraviolet radiation photolyses O3 to O2 and O. Determine the rate at which ozone is consumed by 305nm radiation in a layer of the stratosphere of thickness 1.0 km. The quantum yield is 0.94 at 220K, the concentration about 8 nmol dm−3, the molar absorption coefficient 260 dm3 mol−1 cm−1, and the flux of 305nm radiation about 1×1014 photons cm−2 s−1. Data from W.B. DeMore et al., Chemical kinetics and photochemical data for use in stratospheric modeling: Evaluation Number 11, JPL Publication 94–26 (1994).

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