Consider the mechanism for hydrogen and chlorine: Cl2 + M CI + CI + M,...
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Consider the mechanism for hydrogen and chlorine: Cl2 + M → CI + CI + M, (R1) CI + H2 → HCI + H, (R2) H+ Cl2→ HCI + Cl, (R3) Cl+ Cl + M → Cl2 + M. (R4) (a) With appropriate steady-state assumptions, show that d[HCI] = 2k ka [Cl2 [H2]. dt (b) If NCl3 is added to the mixture as an inhibitor, the following reaction needs to be considered: NCI3 + Cl → NC2 + Cl2. (R5) What is the rate expression in the limit of fast and slow rates of this reaction? Consider the mechanism for hydrogen and chlorine: Cl2 + M → CI + CI + M, (R1) CI + H2 → HCI + H, (R2) H+ Cl2→ HCI + Cl, (R3) Cl+ Cl + M → Cl2 + M. (R4) (a) With appropriate steady-state assumptions, show that d[HCI] = 2k ka [Cl2 [H2]. dt (b) If NCl3 is added to the mixture as an inhibitor, the following reaction needs to be considered: NCI3 + Cl → NC2 + Cl2. (R5) What is the rate expression in the limit of fast and slow rates of this reaction?
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Related Book For
Organic Chemistry structure and function
ISBN: 978-1429204941
6th edition
Authors: K. Peter C. Vollhardt, Neil E. Schore
Posted Date:
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