For each of the following: a. Identify the Nu. b. C. i. Is it strong or...
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For each of the following: a. Identify the Nu. b. C. i. Is it strong or weak? (Use your knowledge of pKa and charges) Identify the E and LG. i. Remember, you can use your knowledge of pKa to determine what is a good LG ii. iii. If there is no Nu, is there a base? If so, identify the base. OTS i. Is the base strong or weak? (Use your knowledge of pKa and charges) ii. Is the base sterically hindered? iii. Is the base non-nucleophilic? d. Identify whether there are incompatible functional groups (with the proposed react in the compound. Provide the expected product(s) of the reaction. e. i. If applicable, give proper stereochemistry of product. ii. Label whether it goes through a: SN1, SN2, E1, E2 mechanism. iii. If no reaction occurs, write NR (No Reaction). Is it sterically hindered or is the o* (of the C-LG bond) accessible? Would the LG leave on its own? (Carbocation stability) CI 'Br + Mel + OTS + + + + e + Na O-Me KⓇO NaCN Br + H₂O + K O-Et Na HN-Ph Li E-Ph For each of the following: a. Identify the Nu. b. C. i. Is it strong or weak? (Use your knowledge of pKa and charges) Identify the E and LG. i. Remember, you can use your knowledge of pKa to determine what is a good LG ii. iii. If there is no Nu, is there a base? If so, identify the base. OTS i. Is the base strong or weak? (Use your knowledge of pKa and charges) ii. Is the base sterically hindered? iii. Is the base non-nucleophilic? d. Identify whether there are incompatible functional groups (with the proposed react in the compound. Provide the expected product(s) of the reaction. e. i. If applicable, give proper stereochemistry of product. ii. Label whether it goes through a: SN1, SN2, E1, E2 mechanism. iii. If no reaction occurs, write NR (No Reaction). Is it sterically hindered or is the o* (of the C-LG bond) accessible? Would the LG leave on its own? (Carbocation stability) CI 'Br + Mel + OTS + + + + e + Na O-Me KⓇO NaCN Br + H₂O + K O-Et Na HN-Ph Li E-Ph
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a Identify the Nu i Is it strong or weak Na OMe Nu OMe Strength Strong b Identify the E and LG i Rem... View the full answer
Related Book For
Income Tax Fundamentals 2013
ISBN: 9781285586618
31st Edition
Authors: Gerald E. Whittenburg, Martha Altus Buller, Steven L Gill
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