Explain the values of the kinetic isotope effect (kH/kD) for the following reactions, indicating what each value means, the reason for the determination made, and the mechanism of each reaction that supports your answer.

 

Transcribed Image Text:

+ HNO3 - 8 N(CH3) CH3 ۵۰۴۰ N-Br + OH + MnO4 * NO₂ + 8 H₂O KH/KD = 1 + N(CH3)3 + H₂O kH/KD = 3.0 = Br 6. & NH kH/KD = 4,9 KH/KD = 7.5 + HNO3 - 8 N(CH3) CH3 ۵۰۴۰ N-Br + OH + MnO4 * NO₂ + 8 H₂O KH/KD = 1 + N(CH3)3 + H₂O kH/KD = 3.0 = Br 6. & NH kH/KD = 4,9 KH/KD = 7.5

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mechanism H Reaction1 H 2 HNO 44 ... View the full answer