rt For Hz the MO wave function has the form: Pspace = N (1s(a) P1s(b)) where
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For Hz" the MO wave function has the form: Pspace = N (1s(a) ± P1s(b)) where a and b are labels for the two protons and N is the normalization constant. a. Show that: N = - where Sab = S Vis(a)Þ1;(b)dr (2+2Sab) b. Show that: Haa + Hab E, = 1+ Sab Наа — Наь and E_ = 1– Sab Where Haa = Hpp = S vis(a)Ĥµ1s(a)dr %3D Hab = S wis(a)A¥15(b)dr For Hz" the MO wave function has the form: Pspace = N (1s(a) ± P1s(b)) where a and b are labels for the two protons and N is the normalization constant. a. Show that: N = - where Sab = S Vis(a)Þ1;(b)dr (2+2Sab) b. Show that: Haa + Hab E, = 1+ Sab Наа — Наь and E_ = 1– Sab Where Haa = Hpp = S vis(a)Ĥµ1s(a)dr %3D Hab = S wis(a)A¥15(b)dr
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Related Book For
Finite Mathematics and Its Applications
ISBN: 978-0134768632
12th edition
Authors: Larry J. Goldstein, David I. Schneider, Martha J. Siegel, Steven Hair
Posted Date:
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