The common building blocks for most high temperature (high Te) super- conductors are copper oxide layers,...

 

Transcribed Image Text:

The common building blocks for most high temperature (high Te) super- conductors are copper oxide layers, as depicted in Figure I.1.6. Assume the distance between copper atoms (filled circles) is a. For simplicity let us also assume that in the third dimension these CuO₂ layers are simply stacked with spacing c, and there are no other atoms in the crystal. In first approximation the layers have a four-fold symmetry; the crystal is tetragonal. Fig. I.1.6. CuO2 lattice (a) Sketch the Bravais lattice and indicate a possible set of primitive vectors for this crystal. What is the unit cell, and what is the basis? (b) In LaCuO4 one discovers, at closer inspection, that the CuO₂ lattice is actually not flat, but that the oxygen atoms are moved a small amount out of the plane ("up" or "down") in an alternating fashion (in Figure I.1.7, a + means up and a means down).4 What is the primitive cell and lattice spac- ing for this crystal? What is the reciprocal lattice? Describe (qualitatively) what happens in the X-ray diffraction pattern as the distortion is decreased gradually to zero. Fig. I.1.7. Distorted CuO2 lattice Ⓡ O 0 Ⓒ e 0 O O The common building blocks for most high temperature (high Te) super- conductors are copper oxide layers, as depicted in Figure I.1.6. Assume the distance between copper atoms (filled circles) is a. For simplicity let us also assume that in the third dimension these CuO₂ layers are simply stacked with spacing c, and there are no other atoms in the crystal. In first approximation the layers have a four-fold symmetry; the crystal is tetragonal. Fig. I.1.6. CuO2 lattice (a) Sketch the Bravais lattice and indicate a possible set of primitive vectors for this crystal. What is the unit cell, and what is the basis? (b) In LaCuO4 one discovers, at closer inspection, that the CuO₂ lattice is actually not flat, but that the oxygen atoms are moved a small amount out of the plane ("up" or "down") in an alternating fashion (in Figure I.1.7, a + means up and a means down).4 What is the primitive cell and lattice spac- ing for this crystal? What is the reciprocal lattice? Describe (qualitatively) what happens in the X-ray diffraction pattern as the distortion is decreased gradually to zero. Fig. I.1.7. Distorted CuO2 lattice Ⓡ O 0 Ⓒ e 0 O O

Answer rating: 100% (QA)

Bocc is 2 Basis Strudue lattice Paramete... View the full answer