There are several limitations of VSEPR in its description of bonding. Consider water and ONE of these molecules - formamide, formic acid, anisole and furan and answer the following questions.

a) What is the main weakness of the VSEPR in each of your select cases?

b) How does the wave function approach to molecular orbitals support the idea of extended conjugation? 

c) Examine the resonance forms presented for the conjugated molecule you have chosen and comment on the distribution of charges which occurs. 

d) All the orbitals discussed in the article are “computationally accurate”using“natural bond orbitals”and an undefined abbreviated term, “B3LYP”. Define each of these terms at a level suited to a student doing CAPE-level chemistry, using an appropriate example. 

e) The authors mention microwave spectroscopy as an experimental tool to check molecular structures. Write a short paragraph on how this works.

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INTRODUCTION Restrictions of VSEPR hypothesis 1VSEPR Theory neglects to clarify isoelectronic species 2 Isoelectronic species alludes to the components that have same number of electrons 3 As indicate... View the full answer