Assuming the presence of a V 12 T 4 defect cluster of the type shown in Figure

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Assuming the presence of a V12T4 defect cluster of the type shown in Figure 2.13, it is possible to build an ordered superstructure for Fe1−xO using a 5a × 5a × 10a unit cell. This supercell would contain 16 vacancy clusters. Calculate the composition.

Figure 2.13

O (a) (b) (c) (d) 

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Solid State Materials Chemistry

ISBN: 9780521873253

1st Edition

Authors: Patrick M. Woodward, Pavel Karen, John S. O. Evans, Thomas Vogt

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