T. Gierczak, R.K. Talukdar, S.C. Herndon, G.L. Vaghjiani, and A.R. Ravish Ankara (J. Phys. Chem. A 101,
Question:
Compute the rate constants at 298 K, and interpret the kinetic isotope effects.
Transcribed Image Text:
A/(dm' mols) 1.13 x 10° 6.0 x 10 1.01 x 10° E,/(k) mol) 14.1 CH, + OH CH,+H,0 CD, + OH CD, + DOH CH, + OD CH, +DOH 17.5 13.6
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The rate constants are k A exp 2231 RT k 113 x 10 dm s mol exp 382 x 106 dm mol s k ...View the full answer
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