Table 3-6 shows that the axial-equatorial energy difference for methyl, ethyl, and isopropyl groups increases gradually: 7.6,
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Energy Differences Between the Axial and Equatorial Conformations of Monosubstituted Cyclohexanes AG (axia-equatorial) (kJ/mol) (kcal/mol) 0.8 0.8 2.1 2.5 0.2 0.2 0.5 0.6 1.0 X Br -OH -COOH -CH -CH2CH axial equatorial 7.6 1.9 -CHCH 8.8 2.1 23 ーC(CH3)3
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The isopropyl group can rotate so that its hydrogen is near the axial hydrogens on carb...View the full answer
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