The compound cisplatin, Pt(NH3)2Cl2, has been studied extensively as an antitumor agent. The reaction for the synthesis of cisplatin is:
Write the electron configuration for platinum ion in cisplatin. Most d8 transition metal ions exhibit square planar geometry. With this and the name in mind, draw’ the structure of cisplatin.
Answer to relevant QuestionsWhat is the electron configuration for the transition metal ion(s) in each of the following compounds? a. (NF4)2[Fe(h2O)2CI4] b. [Co(NH3)2(NH2CH2CH2NH2)2]I2 c. Na2[TaF7] d. [Pt(NH3)4I2][Ptl4] Pt forms +2 and +4 oxidation ...Give formulas for the following. a. Potassium terrachlorocobaltate(II) b. Aquatricarbonylplatinum(II) bromide c. Sodium dicyanobis(oxalato)ferrate(DI) d. Triamminechloroethylenediaminechromium(III) iodide For the process What would be the expected ratio of cis to tram isomers in the product? For the following crystal field diagrams, label each as low spin, high spin, or cannot tell. Explain your answers. a. b. c. How many unpaired electrons are in the following complex ions? a. Ru(NH3)62+ (low-spin case) b. Ni(H2O)62+ c. V(en)33+
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