The reaction illustrated by the equation below is a very general one that can be catalyzed by
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Spectral data for F:
MS (m/z): (after trimethylsilylation): 546, 531
IR (cm-1): 3200 (broad), 1710
1H NMR (δ) (after exchange with D2O): 4.2 (d), 3.9 (m), 3.7 (d), 2.2 (t), and others in the range 1.7 to 1
13C NMR (δ): 172 (C), 74 (CH), 70 (CH2), 67 (CH2), 39 (CH2), and others in the range 32 to 14
(a) What is the structure of product F?
(b) The reaction is intramolecular. Write a mechanism by which it probably occurs.
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Related Book For
Organic Chemistry
ISBN: 978-1118133576
11th edition
Authors: Graham Solomons, Craig Fryhle, Scott Snyder
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