The type of rate law for a reaction, either the differential rate law or the integrated rate law, is usually determined by which data are easiest to collect. Explain.
Answer to relevant Questionsa. Using the free energy profile for a simple one- step reaction, show that at equilibrium K = kf/kr, where kf and kr are the rate constants for the forward and reverse reactions. Hint: Use the relationship ΔGo = 2RT ...The following results were obtained at 600 K for the de-composition of ethanol on an alumina (Al2O3) surface C2H5OH(g) → C2H4(g) + H2O(g) a. Predict PTotal in torr at t = 80. s. b. What is the value of the rate constant, ...Derive the rate law for the production of Cl2 using the steady-state approximation. The gas-phase decomposition 2N2O5 → 4NO2 + O2 is first order but not unimolecular. A possible mechanism is Apply the steady-state approximation to the concentrations of the intermediates NO3 and NO, and derive the rate law ...The hydroxyl radical (OH) is an important oxidizing agent in the atmosphere. At 298 K the rate constant for the reaction of OH with benzene is 1.24 × 10–12 cm3 molecule-1s-1. Calculate the value of the rate constant in L ...
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