You are given vapor pressure data in the form of [T (C). p (mm Hg)] pairs. Construct

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You are given vapor pressure data in the form of [T (°C). p (mm Hg)] pairs. Construct a spreadsheet or write a computer program to perform the following tasks:

(a) Read in Tt, p1, T2, p2,..., TN, pN.

(b) Fit the Clausius—Clapeyron equation to the data using the method of least squares (Appendix A.1) or a fitting routine embedded in the spreadsheet. In completing this task you should find the values of a and b in the formula y = ax + b, where y = In p* and x = 1/(T + 273.2). Print out the values of a and b.

Test your program by fitting the data for ethylene glycol given in Problem 6.4. Then use your formula to estimate the vapor pressures of this substance at 50°C, 80°C, and 110°C, and the boiling points at 760 mm Hg and 2000 mm Hg. In which of the last two values would you have the least confidence? Explain your reasoning.

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Elementary Principles of Chemical Processes

ISBN: 978-0471720638

3rd Edition

Authors: Richard M. Felder, Ronald W. Rousseau

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