Evaluate, by explicit summation, the mean vibrational energy of CCl 4 and plot its value as a
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Evaluate, by explicit summation, the mean vibrational energy of CCl4 and plot its value as a function of temperature. At what temperature is the equipartition value within 5 per cent of the accurate value? Use the wavenumbers 459 cm−1 (symmetric stretch, A), 217 cm−1 (deformation, E), 776 cm−1 (deformation, T), 314 cm−1 (deformation, T).
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The mean vibrational energy of CCl4 is given by E 12 sumni hbar omegai Where E Mean vibration...View the full answer
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Physical Chemistry Thermodynamics And Kinetics
ISBN: 9781464124518
10th Edition
Authors: Peter Atkins, Julio De Paula
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