A formate ester, such as ethyl formate, reacts with an excess of a Grignard reagent to give
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(a) Propose a mechanism to show how the reaction of ethyl formate with an excess of allylmagnesium bromide gives, after protonation, hepta-1,6-dien-4-ol.
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(b) Show how you would use reactions of Grignard reagents with ethyl formate to synthesize the following secondary alcohols. (i) pentan-3-ol (ii) diphenylmethanol (iii) trans,trans-nona-2,7-dien-5-ol
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a b 0 11 HCOEt M...View the full answer
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