G.C.G. Wachewsky, R. Horansky, and V. Vaida (J. Phys. Chem. 100, 11559 (1996)) examined the UV absorption
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(a) Compute the integrated absorption coefficient over a triangular lineshape in the range 31250 to 34483 cm-1 and a maximal molar absorption coefficient of 150 dm3 mol-l cm3 at 31 250 cm-1.
(b) Suppose 1 per cent of the CH) units in a sample at 2.4 Torr and 373 K exist as dimers. Compute the absorbance expected at 31250 cm3 in a sample cell of length 12.0 cm.
(c) Suppose 18 per cent of the CH3I units in a sample at 100 Torr and 373 K exists as dimers. Compute the absorbance expected at 31250 cm-1 in a sample cell of length 12.0 cm; compute the molar absorption coefficient that would be inferred from this absorbance if dimerization was not considered.
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