Molten sodium chloride is to be used as a constant-temperature bath for a high-temperature chemical reactor. Two

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Molten sodium chloride is to be used as a constant-temperature bath for a high-temperature chemical reactor. Two hundred kilograms of solid NaC1 at 300 K is charged into an insulated vessel, and a 3000 kW electrical heater is turned on, raising the salt to its melting point of 1073 K and melting it at a constant pressure of 1 atm.

(a) The heat capacity (Cp) of solid NaC1 is 50.41 J/(mol ∙ K) at T 300 K. and 53.94 J/(mol ∙ K) at T = 500 K. and the heat of fusion of NaC1 at 1073 K is 30.21 kJ/mol. Use these data to determine a linear expression for Cp (T) and to calculate .H(kJ/mol) for the transition of NaC1 from a solid at 300 K to a liquid at 1073 K.

(b) Write and solve the energy balance equation for this closed system isobaric process to determine the required heat input in kilojoules.

(c) If 85% of the full power of 3000 kW goes into heating and melting the salt, how long does the process take?

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Elementary Principles of Chemical Processes

ISBN: 978-0471720638

3rd Edition

Authors: Richard M. Felder, Ronald W. Rousseau

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