One of the earliest commercial plastics was Bakelite, formed by the reaction of phenol with a little

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One of the earliest commercial plastics was Bakelite®, formed by the reaction of phenol with a little more than one equivalent of formaldehyde under acidic or basic conditions. Baeyer first discovered this reaction in 1872, and practical methods for casting and molding Bakelite® were developed around 1909. Phenol-formaldehyde plastics and resins (also called phenolics) are highly cross-linked because each phenol ring has three sites (two ortho and one para) that can be linked by condensation with formaldehyde. Suggest a general structure for a phenol-formaldehyde resin, and propose a mechanism for its formation under acidic conditions.
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Organic Chemistry

ISBN: 978-0321768414

8th edition

Authors: L. G. Wade Jr.

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