Consider the process shown in the figure. A bulk gas stream containing 0.10 mole% of carbon monoxide

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Consider the process shown in the figure. A bulk gas stream containing 0.10 mole% of carbon monoxide (CO) gas, 2.0 mole% O2gas, and 97.9 mole% of CO2gas flows over a flat catalytic surface of length 0.50 m at a bulk velocity of 40 m/s at 1.0 atm and 600 K. Heat-transfer processes maintain the gas stream and catalytic surface at 600 K. At this temperature, the catalytic surface promotes the oxidation reaction CO(g) + 1/2O2(g) †’ CO2(g). Let A = CO, B = O2, C = CO2. The gas-phase diffusion coefficients at 1.0 atm and 300 K are DAB= 0.213 cm2/s, DAC= 0.155 cm2/s, DBC = 0.166 cm2/s. 

a. What are the Schmidt numbers for CO and O2 mass transfer? What species (CO, O2, CO2) is considered the carrier gas? 

b. For CO mass transfer, what is the average convective mass- transfer coefficient (kc) over the 0.50 m length of the catalytic surface, and the local mass transfer coefficient (kc,x) at the far edge of the catalytic surface (x = L = 0.50 m)? 

c. Using boundary-layer theory, scale kc for CO mass transfer to kc for O2 transfer. 

d. At 600 K, the surface reaction constant for the first-order oxidation reaction with respect to CO concentration is ks = 1.5 cm/s. What is the average molar flux of CO to the catalytic surface, assuming that the composition of CO in the bulk gas is maintained at 0.10 mole%?600 K, 1.0 atm V= 40 m/s 0.1 mole% CO 2.0 mole% O2 97.9 mole% CO2 CO(A) + 1/20,(B) CO2 (C) Сдя NA CAs catalyst surfac

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Fundamentals Of Momentum Heat And Mass Transfer

ISBN: 9781118947463

6th Edition

Authors: James Welty, Gregory L. Rorrer, David G. Foster

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