The UNILAN equation for pure-species adsorption is: where m, s, and c are positive empirical constants. (a)
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The UNILAN equation for pure-species adsorption is:
where m, s, and c are positive empirical constants.
(a) Show that the UNILAN equation reduces to the Langmuir isotherm for s = 0.
(b) Show that Henry’s constant k for the UNILAN equation is:
(c) Examine the detailed behavior of the UNILAN equation at zero pressure (P → 0, n → 0).
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ANSWER a For s 0 the UNILAN equation becomes n m2s lnc Pc P m20 ln1 0 This means that there is ...View the full answer
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Related Book For 
Introduction To Chemical Engineering Thermodynamics
ISBN: 9781259696527
8th Edition
Authors: J.M. Smith, Hendrick Van Ness, Michael Abbott, Mark Swihart
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