Consider a quantum system with just three linearly independent states. Suppose the Hamiltonian, in matrix form, is

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Consider a quantum system with just three linearly independent states. Suppose the Hamiltonian, in matrix form, is

where V0 is a constant, and ϵ is some small number (∈ << 1).
(a) Write down the eigenvectors and eigenvalues of the unperturbed Hamiltonian (∈ = 0).

(b) Solve for the exact eigenvalues of H. Expand each of them as a power series in ϵ, up to second order.
(c) Use first- and second-order non-degenerate perturbation theory to find the approximate eigenvalue for the state that grows out of the nondegenerate eigenvector of H0. Compare the exact result, from (b).
(d) Use degenerate perturbation theory to find the first-order correction to the two initially degenerate eigenvalues. Compare the exact results.

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Introduction To Quantum Mechanics

ISBN: 9781107189638

3rd Edition

Authors: David J. Griffiths, Darrell F. Schroeter

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