A dilute solution of a weak (1,1)-electrolyte contains both neutral ion pairs and ions in equilibrium (AB
Question:
A dilute solution of a weak (1,1)-electrolyte contains both neutral ion pairs and ions in equilibrium (AB ⇌ A+ +B−). Prove that molar conductivities are related to the degree of ionization by the equations:
where Λm° is the molar conductivity at infinite dilution and K is the constant in Kohlrausch’s law.
Transcribed Image Text:
1 1 (1-α).m Am Am(α)'a'Am(α) + Am(a)= Am-K(ac)1/2
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Related Book For
Physical Chemistry Thermodynamics And Kinetics
ISBN: 9781464124518
10th Edition
Authors: Peter Atkins, Julio De Paula
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