A general way to calculate the number of states that arise from a given configuration is as

Question:

A general way to calculate the number of states that arise from a given configuration is as follows. Calculate the combinations of ml and ms for the first electron, and call that number n. The number of combinations used is the number of electrons, which we call m. The number of unused combinations is n − m. According to probability theory, the number of distinct permutations that arise from distributing the m electrons among the n combinations is n! / [m!(n – m)!]. For example, the number of states arising from a p2 configuration is 6! / [2!4!] = 15, which is the result obtained in Section 22.2. Using this formula, calculate the number of possible ways to place five electrons in a d subshell. What is the ground-state term for the d5 configuration and how many states does the term include?

Fantastic news! We've Found the answer you've been seeking!

Step by Step Answer:

Related Book For  book-img-for-question

Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

Question Posted: