Consider the following isotope-exchange reaction: DCl (g) + HBr (g) DBr (g) + HCl (g) The amount
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DCl (g) + HBr (g) ‡„ DBr (g) + HCl (g)
The amount of each species at equilibrium can be measured using proton and deuterium NMR (see Journal of Chemical Education 73 [1996]: 99). Using the spectroscopic information below, determine KP for this reaction at 298 K. For this reaction, Δε = 41 cmˆ’1, equal to the difference in zero-point energies between products versus reactants, and the ground-state electronic degeneracy is zero for all species.
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For DBr Notice that the vibrational partition function is approximately equal to on...View the full answer
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