Consider the gas-phase isomerization of cyclopropane. Are the following data of the observed rate constant as a
Question:
Are the following data of the observed rate constant as a function of pressure consistent with the Lindemann mechanism?
Transcribed Image Text:
CH, CH,CH=CH2 CH,-CH2 k (10ʻs-1) 2.98 2.82 P (Torr) 84.1 к (10'5-1) P (Torr) 1.37 1.30 0.569 0.170 0.857 0.486 34.0 2.23 11.0 6.07 2.00 0.120 0.392 0.067 2.89 1.54 0.303
Fantastic news! We've Found the answer you've been seeking!
Step by Step Answer:
Answer rating: 86% (15 reviews)
If the data obeyed the Lindemann mechanism then a plot of the data would fit the equ...View the full answer
Answered By
Ayush Jain
Subjects in which i am expert:
Computer Science :All subjects (Eg. Networking,Database ,Operating System,Information Security,)
Programming : C. C++, Python, Java, Machine Learning,Php
Android App Development, Xamarin, VS app development
Essay Writing
Research Paper
History, Management Subjects
Mathematics :Till Graduate Level
5.00+
1+ Reviews
10+ Question Solved
Related Book For
Question Posted:
Students also viewed these Sciences questions
-
The isomerization of cyclopropane, C3H6, to propylene, CH2=CHCH3, is first order in cyclopropane and first order overall. At 1000oC, the rate constant is 9.2/s. What is the half-life of cyclopropane...
-
The isomerization of cyclopropane, C3H6, is believed to occur by the mechanism shown in the following equations: Here C3H6* is an excited cyclopropane molecule. At low pressure, Step 1 is much slower...
-
From the following data for the first-order gas-phase isomerization of CH3NC at 215 oC, calculate the first-order rate constant and half-life for the reaction: Time (s) Pressure CH3NC (torr)...
-
Find the exact value of sin(x - y) if sin(x) = 3T 3T T
-
Use the graph of the function f to create a table of values for the given points. Then create a second table that can be used to find f-1, and sketch the graph of f-1, if possible. 1. 2. y 4. + 2 4...
-
JPJ Corp has sales of $1 million, accounts receivable of $50,000, total assets of $5 million (of which $3 million are fixed assets), inventory of $150,000, and cost of goods sold of $600,000. What is...
-
Use the Minitab macro NormDP to nd the posterior distribution of the mean when we have a random sample of observations from a normal(, 2 ), where 2 is known, and we have a discrete prior for ....
-
The Electrotech Corporation manufactures two industrial-sized electrical devices: generators and alternators. Both of these products require wiring and testing during the assembly process. Each...
-
(a) Discuss four benefits that would accrue to a foreign investor investing in the international bonds and (b) Highlight four conditions that must be met by a subsidiary before it could be considered...
-
During the current year, Zeta Corporation distributes the assets listed below to its sole shareholder, Susan. For each asset listed, determine the gross income recognized by Susan, her basis in the...
-
In the discussion of the Lindemann mechanism, it was assumed that the rate of activation by collision with another reactant molecule, A, was the same as collision with a nonreactant molecule, M, such...
-
Consider the following mechanism, which results in the formation of product P: If only the species A is present at t = 0, what is the expression for the concentration of P as a function of time? You...
-
A company that uses a natural business year, or ends its year when business is at a peak, will tend to distort the liquidity of its receivables when end-of-year and beginning-of-year receivables are...
-
Which alternative is better? probability of soft kill of each three alternatives against each of three threats. in addition, the relative frequency of attacks is 40% by country 1, 50% by country 2,...
-
How do protein conformational changes, such as allosteric transitions, modulate enzymatic activity and cellular signaling cascades?
-
4. Find the entire solution for the following system: y[n] = 0.9y[n-1]+x[n] h[n] = (0.9)" u[n] x[n] = u[n] y[-1] = 1 5. Find the values a and for the following y[n] = 0.8y[n-1]+x[n] h[n] = (0.8)"...
-
Could you explain the principles of protein folding kinetics and thermodynamics, and their implications in protein misfolding diseases?
-
For Taylor Corporation, the working capital at the end of the current year is $10,000 more than the working capital at the end of the preceding year, reported as follows: Year 2 Year 1 Current...
-
A completely absorbing screen receives 300 W of light for 100 s. Compute the total linear momentum transferred to the screen.
-
The roof of a refrigerated truck compartment is of composite construction, consisting of a layer of foamed urethane insulation (t2 = 50 mm, ki = 0.026 W/m K sandwiched between aluminum alloy panels...
-
An equimolar mixture of H 2 and CO is obtained by the reaction of steam with coal. The product mixture is known as water-gas. To enhance the H 2 content, steam is mixed with water-gas and passed over...
-
For the systems specified below, obtain residue curve maps and plot the range of possible distillate and bottoms compositions for the given feeds. UNIQUAC parameters are provided. (a) methanol(1) +...
-
(a) Rank the following molecules in order of increasing oxidation of carbon and give the oxidation state of C for each: CO2, -COH(aldehyde), -COOH(carboxylic acid), -CO- (ketone), -COH(alcohol),...
-
To what extent does the digital revolution augment or diminish the traditional mechanisms of social capital formation and maintenance, particularly in the context of virtual communities and online...
-
As a project manager, what project component should you focus on to minimize the likelihood of incurring changes to the project budget or extensions in the project timeline?
-
What is game theory? How does it relate to strategic decision making? What do the phrases dominant strategy and Nash Equilibrium mean as they apply to game theory?
Study smarter with the SolutionInn App