Consider the gas-phase isomerization of cyclopropane. Are the following data of the observed rate constant as a

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Consider the gas-phase isomerization of cyclopropane.

CH, CH,CH=CH2 CH,-CH2

Are the following data of the observed rate constant as a function of pressure consistent with the Lindemann mechanism?

k (10ʻs-1) 2.98 2.82 P (Torr) 84.1 к (10'5-1) P (Torr) 1.37 1.30 0.569 0.170 0.857 0.486 34.0 2.23 11.0 6.07 2.00 0.12

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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Question Posted: May 18, 2018 01:05 AM

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Consider the gas-phase isomerization of cyclopropane. Are the following data of the observed rate constant as a

Question:

CH, CH,CH=CH2 CH,-CH2 k (10ʻs-1) 2.98 2.82 P (Torr) 84.1 к (10'5-1) P (Torr) 1.37 1.30 0.569 0.170 0.857 0.486 34.0 2.23 11.0 6.07 2.00 0.120 0.392 0.067 2.89 1.54 0.303

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If the data obeyed the Lindemann mechanism then a plot of the data would fit the equ...View the full answer

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