Consider the unimolecular isomerization of methylcyanide, a reaction that will be discussed in detail in Chapter 36:

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Consider the “unimolecular” isomerization of methylcyanide, a reaction that will be discussed in detail in Chapter 36:

CH3NC(g) → CH3CN(g)

The Arrhenius parameters for this reaction are A = 2.5 × 1016 s–1 and Ea = 272 kJ mol–1. Determine the Eyring parameters ΔH and ΔS for this reaction with T = 300.K.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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