For phenanthrene, the measured lifetime of the triplet state ( p ) is 3.3 s, the fluorescence

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For phenanthrene, the measured lifetime of the triplet state (τ p) is 3.3 s, the fluorescence quantum yield is 0.12, and the phosphorescence quantum yield is 0.13 in an alcohol–ether glass at 77 K. Assume that no quenching and no internal conversion from the singlet state occurs. Determine k p, k T isc, and k S isc / k f.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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