If the reaction Fe 2 N(s) + 3/2H 2 (g) 2Fe(s) + NH 3 (g) comes

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If the reaction Fe2N(s) + 3/2H2(g) ⇋ 2Fe(s) + NH3(g) comes to equilibrium at a total pressure of 1 bar, analysis of the gas shows that at 700. and 800. K, PNH3 /PH2 = 2.165 and 1.083, respectively, if only H2(g) was initially present in the gas phase and Fe2N(s) was in excess.

a. Calculate KP at 700. and 800. K.

b. Calculate ΔSoR at 700. K and 800. K and ΔHoR assuming that it is independent of temperature.

c. Calculate ΔGoR for this reaction at 298.15 K.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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