In discussing the Boltzmann distribution in Chapter 13, we used the symbols gi and gj to indicate

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In discussing the Boltzmann distribution in Chapter 13, we used the symbols gi and gj to indicate the degeneracies of the energy levels i and j. By degeneracy, we mean the number of distinct quantum states (different quantum numbers) all of which have the same energy.

a. Using your answer to Problem P15.17a, what is the degeneracy of the energy level 9h2/8 ma2 for the square two-dimensional box of edge length a?

b. Using your answer to Problem P15.14b, what is the degeneracy of the energy level 17h2/8 ma2 for a three dimensional cubic box of edge length a?

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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