The Doppler broadening in a gas can be expressed as where M is the molar mass. For

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The Doppler broadening in a gas can be expressed as

Av = (2vo/c)/2 In2(RT/M))

where M is the molar mass. For the sodium

Bp P3/2 → 3s S1/2

transition, ν0 5.0933 Ã— 1014 s-1. Calculate Δν and Δν /ν0 at 500.K.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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