Molten iron-carbon solution is in equilibrium with CO-CO2 gas mixture. Calculate the carbon activities in liquid iron
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Question:
Molten iron-carbon solution is in equilibrium with CO-CO2 gas mixture. Calculate the carbon activities in liquid iron for the following compositions at 1833 K. Please indicate the standard state for carbon in your answers:-
Given
(l) P2co/Pc02 ratio in the gas mixture in equilibrium with iron-carbon melt as a function of the carbon concentration at 1833 K:
%C | 0.15 | 0.36 | O .49 | 0.60 | 0.79 | 0.88 | 1.02 |
P2co/Pc02 (MPa) | 10. I | 20.6 | 29.9 | 41.2 | 51.5 | 66.7 | 80.8 |
(2) Equilibrium constant K for the reaction
+ C02 - 2CO, log K = -8199/T + 8.66
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