Sulfur tetra-fluoride (SF4) reacts slowly with O2 to form sulfur tetra-fluoride monoxide (OSF4) according to the following

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Sulfur tetra-fluoride (SF4) reacts slowly with O2 to form sulfur tetra-fluoride monoxide (OSF4) according to the following unbalanced reaction:
SF4 (g) + O2 (g) †’ OSF4 (g)
The O atom and the four F atoms in OSF4 are bonded to a central S atom.
(a) Balance the equation.
(b) Write a Lewis structure of OSF4 in which the formal charges of all atoms are zero.
(c) Use average bond enthalpies (Table 8.4) to estimate the enthalpy of the reaction. Is it endothermic or exothermic?
(d) Determine the electron-domain geometry of OSF4, and write two possible molecular geometries for the molecule based on this electron-domain geometry.
(e) Which of the molecular geometries in part (d) is more likely to be observed for the molecule? Explain.
Sulfur tetra-fluoride (SF4) reacts slowly with O2 to form sulfur
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Chemistry The Central Science

ISBN: 978-0321696724

12th edition

Authors: Theodore Brown, Eugene LeMay, Bruce Bursten, Catherine Murphy, Patrick Woodward

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