The kinetics of acetone hydrogenation on Pt catalysts has been studied by Sen and Vannice (See Problem

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The kinetics of acetone hydrogenation on Pt catalysts has been studied by Sen and Vannice (See Problem 7.9) [35]. To determine which bonding mode is more probable, the heat of adsorption for an on-top ת1 μ2 adsorbed acetone species was compared to that for a di-s-bonded ת2 μ2 species which had a C atom and the O atom interacting with a close-packed Pt (111) surface. What are these two values? Which species is favored?
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Organic Chemistry

ISBN: 978-0072905014

4th edition

Authors: Francis A. Carey

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