Tri-butyltin hydride (Bu3SnH) is used synthetically to reduce alkyl halides, replacing a halogen atom with hydrogen. Free-radical
Question:
The following bond-dissociation enthalpies may be helpful:
(a) Propose initiation and propagation steps to account for this reaction.
(b) Calculate values of ÎH for your proposed steps to show that they are energetically feasible.
Transcribed Image Text:
trace Br, Inv BrBuSnH H + + BuSnBr Br B 192 kJ/mol H-Br 368 kJ/mol BujSn H 310 kJ/mol Bu3Sn Br 552 kJ/mol Br 397 kJ/mol 285 kJ/mol
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a b All energies are in kJmole The abbreviation c Hx stands for the cyclo hexane ring Step 2 ...View the full answer
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