When the 1HNMR spectrum of an alcohol is run in dimethyl sulfoxide (DMSO) solvent rather than in
Question:
When the 1HNMR spectrum of an alcohol is run in dimethyl sulfoxide (DMSO) solvent rather than in chloroform, exchange of the O—H proton is slow and spin—spin splitting is seen between the O—H proton arid C—H protons on the adjacent carbon. What spin multiplicities would you expect for the hydroxyl protons in the following alcohols?
(a) 2-Methyl-2-propanol
(b) Cyclohexanol
(c) Ethanol
(d) 2-Propanol
(e) Cholesterol
(f) 1-Methylcyclohexanol
Fantastic news! We've Found the answer you've been seeking!
Step by Step Answer:
Answer rating: 100% (12 reviews)
Under conditions of slow exchange the OH signal of a tertiary alco...View the full answer
Answered By
Abigael martinez
I have been a tutor for over 3 years and have had the opportunity to work with students of all ages and backgrounds. I have a strong belief that all students have the ability to learn and succeed if given the right tools and support. I am patient and adaptable, and I take the time to get to know each student's individual learning style in order to best support their needs. I am confident in my ability to help students improve their grades and reach their academic goals.
5.00+
1+ Reviews
10+ Question Solved
Related Book For
Question Posted:
Students also viewed these Organic Chemistry questions
-
The 1HNMR spectrum of the alkyl bromide used to make the ylide to form a compound with molecular formula C11H14 is shown below. What product is obtained from the Wittig reaction? 10 (ppm) frequency
-
What type of time-series components would you expect for the following products and services? a. Monthly sales of a retail florist. b. Monthly sales of milk in a supermarket. c. Daily demand for...
-
The 1HNMR spectrum of D-glucose in D2O exhibits two high-frequency (low-field) doublets. What is responsible for these doublets?
-
In August 2014, Jim acquired a 99-year lease on a flat for 170,000. In August 2020, he assigned the lease to Shirley for 212,000. The flat was never Jim's residence. Compute the chargeable gain.
-
When would multi business companies find the portfolio approach to strategic analysis and choice useful?
-
What is the appropriate test procedure for the hypotheses in Problem 8.31? Pulmonary Disease A possible important environmental determinant of lung function in children is the amount of cigarette...
-
\(X\) is the number of bits in error in the next four bits transmitted. What is the expected value of the square of the number of bits in error? Now, \(h(X)=X^{2}\). Therefore, \[ \begin{aligned}...
-
Each of the following cost items pertains to one of the following companies: Toyota (a manufacturing-sector company), Sobeys (a merchandising-sector company), and Google (a service-sector company):...
-
A 2.00-kg block of copper at 19.0C is dropped into a large vessel of liquid nitrogen at 77.3 K. How many kilograms of nitrogen boil away by the time the copper reaches 77.3 K? (The specific heat of...
-
Bruce also requires a calculation of taxable income for the most recent year ended December 31, 2019. The calculation should be prepared in Excel. He has also requested that you prepare the year-end...
-
Assume that you need to prepare 5-cholesten-3-one from cholesterol. How could you use IR spectroscopy to tell whether the reaction was successful? What differences would you look for in the IR...
-
Give IUPAC names for the following compounds: (a) (b) (c) (d)
-
What is marking-to-market for a future? Why is this marking-to-market important for reducing counterparty risk?
-
How do regulatory frameworks and public policy initiatives influence innovation dynamics, including the balance between fostering innovation and addressing concerns related to privacy, security, and...
-
Mr. Ram is marrried and has a son. Mr Ram paid his tuition $ 9,000 for his son. His son has net income of $ 2,200. all of which is employment income earned during the summer months. He will transfer...
-
Is accounting for goodwill controversial? Why does some believe that goodwill's value eventually disappears? Explain why do some argue that companies should charge goodwill to expense over the...
-
List and Discuss the different types of factual information you would need to find for your client's case in each of the following areas of practice and 2. Specify specifically where you could...
-
Chandler and Cassidy are married and file a joint return. Chandler is age 66, and Cassidy is age 68. They report the following income items: Dividend eligible for 0% preferential rate Capital gain...
-
Luke Lumberjack is being tried for raping a woman he has known for a year. The states evidence disclosed that Lumberjack, age twenty-three, had spent an evening with the female complainant, age...
-
Determine the reactions in supports A and D and connections B and C. Sketch its shear and moment diagram and determine the magnitude ankoration of the maximum shear and moment for every member. 18 3...
-
The fcc unit cell is a cube with atoms at each of the corners and in the center of each face, as shown here. Copper has the fcc crystal structure. Assume an atomic radius of 128 pm for a Cu atom. (a)...
-
Write a bond-line formula for each of the following compounds: (a) 1, 4-Dichloropentane (b) sec-Butyl bromide (c) 4-Isopropylheptane (d) 2, 2, 3-Trimethylpentane (e) 3-Ethyl-2-methylhexane (f) 1,...
-
Give systematic IUPAC names for each of the following: (a) (b) (c) (d) (e) (f) (g) (h) Br Br Cl
-
Show by a calculation (using the formula Go = -RT ln Keq) that a free-energy difference of 7.6 kJ mol-1 between the axial and equatorial forms of methylcyclohexane at 25oC (with the equatorial form...
-
(a) Given that z =2+23i and z =-5+5i. Express, and in polar form. (b) Find z and in exponential form. (c) Find (5)*() in the forms of x+yi.
-
Evaluate the impact of mobile banking on traditional revenue streams and business models of banks, such as transaction fees, interchange fees, and overdraft charges. How do banks monetize mobile...
-
1. Researchers wanted to see how two new varieties of fish food compare to a commonly used food. They took 180 similar fish and assigned them randomly to three different tanks. The fish in tank 1...
Study smarter with the SolutionInn App