(a) Using the information given in Sections 3-6 and 3-7, write the products of the radical monochlorination...
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(i) Pentane and
(ii) 3-methylpentane.
(b) For each, estimate the ratio of the isomeric monochlorination products that would form at 25°C.
(c) Using the bond strength data from Table 3-1, determine the ∆H° values of the propagation steps for the chlorination of 3-methylpentane at C3. What is the overall ∆H° value for this reaction?
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Organic Chemistry structure and function
ISBN: 978-1429204941
6th edition
Authors: K. Peter C. Vollhardt, Neil E. Schore
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