By measuring the temperature change accompanying a differential volume change in a free expansion across a valve
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By measuring the temperature change accompanying a differential volume change in a free expansion across a valve and separately in a reversible adiabatic expansion, the two derivatives (∂T/∂V )H and (∂T/∂V )S can be experimentally evaluated.
a. Develop expressions for these derivatives in terms of the more fundamental quantities.
b. Evaluate these derivatives for a van der Waals fluid.
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a To develop expressions for the derivatives TV H and TV S in terms of more fundamental quantities w...View the full answer
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Related Book For
Chemical Biochemical And Engineering Thermodynamics
ISBN: 9780470504796
5th Edition
Authors: Stanley I. Sandler
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