The critical temperature of benzene is 289C and its critical pressure is 4.89 MPa. At 220C its
Question:
The critical temperature of benzene is 289°C and its critical pressure is 4.89 MPa. At 220°C its vapor pressure is 1.91 MPa.
a. Calculate the fugacity of liquid benzene in equilibrium with its pure vapor at 220°C.
b. Repeat the calculation for the case in which liquid benzene is under an atmosphere of hydrogen such that the total pressure is 13.61 MPa. The average density of liquid benzene at these conditions is 0.63 g/cc, and you can assume that hydrogen is insoluble in benzene at this temperature. The molecular weight of benzene is 78.02.
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Step by Step Answer:
a To calculate the fugacity of liquid benzene in equilibrium with its pure vapor at 220C we can use the Antoine equation to estimate the vapor pressure of benzene at this temperature log10P A B T C wh...View the full answer
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Related Book For 
Chemical Biochemical And Engineering Thermodynamics
ISBN: 9780470504796
5th Edition
Authors: Stanley I. Sandler
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