Identification of the hybridization of an atom in a molecule can often act as a good guide

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Identification of the hybridization of an atom in a molecule can often act as a good guide to the kind of chemical reactions it can undergo and help in the interpretation of its spectroscopic observations. What is the hybridization of phosphorus in PF5?

ANTICIPATE To form five bonds, five hybrid orbitals are needed, which suggests that a d-orbital should be involved as well as the four s- and p-orbitals of a valence shell.

PLAN Choose the hybridization scheme to match the electron arrangement predicted by the VSEPR model, using N atomic orbitals to form N hybrid orbitals.

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Chemical Principles The Quest For Insight

ISBN: 9781464183959

7th Edition

Authors: Peter Atkins, Loretta Jones, Leroy Laverman

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