Show that the van der Waals parameter b is related to the molecular volume V mol ,
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Show that the van der Waals parameter b is related to the molecular volume Vmol, the volume occupied by one molecule, by b = 4NAVmol. Treat the molecules as spheres of radius r, so that Vmol = 4/3πr3. The closest that the centers of two molecules can approach is 2r.
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Related Book For
Chemical Principles The Quest For Insight
ISBN: 9781464183959
7th Edition
Authors: Peter Atkins, Loretta Jones, Leroy Laverman
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