The concentration of nitrate ion can be determined by a multistep process. A sample of water of

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The concentration of nitrate ion can be determined by a multistep process. A sample of water of volume 25.00 mL from a rural well contaminated with NO3(aq) was made basic and treated with an excess of zinc metal, which reduces the nitrate ion to ammonia. The evolved ammonia gas was passed into 50.00 mL of 2.50 * 10–3 m HCl(aq). The unreacted HCl(aq) was titrated to the stoichiometric point with 28.22 mL of 1.50 * 10–3 m NaOH(aq).

(a) Write balanced chemical equations for the three reactions.

(b) What is the molar concentration of nitrate ion in the well water?

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Chemical Principles The Quest For Insight

ISBN: 9781464183959

7th Edition

Authors: Peter Atkins, Loretta Jones, Leroy Laverman

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