In the gas phase, acetic acid exists as an equilibrium of monomer and dimer molecules. (The dimer

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In the gas phase, acetic acid exists as an equilibrium of monomer and dimer molecules. (The dimer consists of two molecules linked through hydrogen bonds.)image

The equilibrium constant, Kc, at 25°C for the monomer–dimer equilibrium2 CH3COH (CH3COH)2

has been determined to be 3.2 × 104. Assume that acetic acid is present initially at a concentration of 5.4 × 10−4 mol/L at 25°C and that no dimer is present initially.
(a) What percentage of the acetic acid is converted to dimer?
(b) As the temperature increases, in which direction does the equilibrium shift? (Recall that hydrogen-bond formation is an exothermic process.)

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Chemistry And Chemical Reactivity

ISBN: 9780357001172

10th Edition

Authors: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

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