Use Figure 22-17 to establish E for the reduction of NO 3 to NO 2
Question:
Use Figure 22-17 to establish E° for the reduction of NO3– to NO2– in a basic solution.
Figure 22-17
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Acidic solution ([H+] = 1 M): +5 +3 +4 +2 +1 0 - 1 1.42 V 0.803 V 1.065 V 0.996 V 1.591 V 1.766 V -1.87 V NO3-N₂04 HNO₂ NO N₂0 N₂NH3OH+———N₂H5+———NH4+ Basic solution ([OH-] = 1 M): +5 +4 +3 +2 +1 -0.86 V 0.867 V -0.46 V 0.76 V NO3-N204- NO₂ NO -2 ― -3 1.275 V -2 0 -1 0.94 V-3.04 V 0.73 V N₂ON₂NH₂OHN₂H4NH3 -3 0.10 V
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Related Book For
General Chemistry Principles And Modern Applications
ISBN: 9780132931281
11th Edition
Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette
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