(a) Give equations to show the effect of temperature on the reaction between Cl 2 and aqueous...

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(a) Give equations to show the effect of temperature on the reaction between Cl2 and aqueous NaOH.

(b) In neutral solution 1 mol [IO4] reacts with excess I to produce 1 mol I2. On acidification of the resulting solution, a further 3 mol I2 is liberated. Derive equations for the reactions which occur under these conditions.

(c) In strongly alkaline solution containing an excess of barium ions, a solution containing 0.01587 g of I was treated with 0.1M [MnO4] until a pink colour persisted in the solution; 10.0cm3 was required. Under these conditions, [MnO4] was converted into the sparingly soluble BaMnO4. What is the product of the oxidation of iodide?

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Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

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