Enthalpies of hydration and values of the ligand-field splitting parameter, O , are given for some
Question:
Enthalpies of hydration and values of the ligand-field splitting parameter, ΔO, are given for some octahedrally coordinated ions.
(a) Plot the enthalpies of hydration against the number of d electrons.
(b) Calculate LFSE in terms of ΔO for high-spin configuration. Use the given values of ΔO to find LFSE in kJ mol−1 for each ion.
(c) Apply this energy as a correction term to the enthalpies of hydration and plot the estimated ΔH in the absence of ligand-field effects. Comment on this plot. (1 kJ mol−1 = 83.7 cm−1.)
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To address your questions well go through each part step by step a Plot of Enthalpies of Hydration vs Number of d Electrons Lets plot the enthalpies o...View the full answer
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Related Book For 
Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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