Equation 18.27 showed the preparation of [F 3 AsAuXe][Sb 2 F 11 ] from [F 3 AsAu][SbF

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Equation 18.27 showed the preparation of [F3AsAuXe][Sb2F11] from [F3AsAu][SbF6]. Solid [F3AsAu][SbF6] contains a distorted [SbF6] ion; one Sb–F bond is 193 pm, and five are in the range 185–189pm. The Au centre interacts with the F atom of the long Sb–F bond (Au–F = 212pm, compared with 203 pm calculated for the hypothetical [AuF2] ion). Suggest why [F3AsAu][SbF6] was chosen as the precursor to [F3AsAuXe]+, rather than a route involving reduction of AuF3 in anhydrous HF/SbF5 in the presence of Xe.

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Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

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