Figure 21.24 (which is based on J.B. Goddard and F. Basolo, Inorg. Chem., 1968, 7, 936) shows
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Figure 21.24 (which is based on J.B. Goddard and F. Basolo, Inorg. Chem., 1968, 7, 936) shows the observed first-order rate constants for the reaction of [PdBrL]+ with various Y− to give [PdYL]+, where L is Et2NCH2CH2NHCH2CH2NEt2. Note the large slope for S2O32− and zero slopes for Y− = N3− , I− , NO2−, and SCN−. Propose a mechanism.
Figure 21.24.
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1 Large Slope for S 2 O 3 2 The large slope for S 2 O 3 2 suggests that this species is likely invol...View the full answer
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Related Book For 
Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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