Under ambient conditions lithium and sodium adopt simple bcc structures. Under high pressures these alkali metals undergo
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Under ambient conditions lithium and sodium adopt simple bcc structures. Under high pressures these alkali metals undergo a series of complex phase transitions to fcc and then lowersymmetry structures (M.I. McMahon et al., Proc. Natl. Acad. Sci. USA, 2007, 104, 17297; B. Rousseau et al., Eur. Phys. J. B, 2011, 81, 1). Discuss these phase transitions and the changes in electronic properties that accompany them.
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The phase transitions of lithium Li and sodium Na under high pressures from their simple bodycentered cubic bcc structures to more complex facecentered cubic fcc and lower symmetry structures are fasc...View the full answer
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Related Book For 
Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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